You will do get an opportunity to do a Practice Interview, these can be taken several times so you can get comfortable with the process. It also gives you a chance to ensure that your webcam & microphone is working. When you log in you'll see the button to "Start Practicing" which brings you into this stage of the process.
When you've completed that and are happy all is in order. You will proceed finally to start your actual interview. This is your real live interview and you can only do this one once. As soon as you click on "start interview" you are committed to this stage of the process.
Depending on the client you are interviewing for you may or may not see the option to "review your interview"